frankdux,
All email templates can be found in skin1/mail and skin1/mail/html - ones in mail are typically for text-based emails and the ones in html are for html-included emails - settings for that are indeed under your email settings.
Ones with a prefix "order_" for the most part cover emails regarding orders. You can either edit the existing ones, or even create your own making sure to use a proper include for your newly created email template.
For now, it would be recommended you backup your existing templates, then edit existing to reflect your preference.
HTH
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