You should alter:
skin/common_files/lib/jqueryui/jquery.ui.theme.css
OR
skin/%your_current_skin%/lib/jqueryui/jquery.ui.theme.css
Find in the code something like this and click the link to visually configure the theme:
Once you've done save the theme upload to the same location renaming to X-Cart style.
Update:
http://help.qtmsoft.com/index.php?title=X-Cart:Customizing_storefront#How_to_change_popup_di alog_colors_and_layout.3F